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III. Long Answer Questions · Q13

Q.Explain in detail the isothermal process.

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Step 1. An isothermal process is one in which the system's temperature stays constant while pressure and volume vary. Substituting fixed TT into PV=μRTPV=\mu RT gives PV=constantPV=\text{constant}, so a gas moving from (P1,V1)(P_1,V_1) to (P2,V2)(P_2,V_2) satisfies P1V1=P2V2P_1V_1=P_2V_2.

Step 2. On a P-V diagram this traces a hyperbola called an isotherm; since P∝1/VP\propto1/V, a curve closer to the origin corresponds to a lower temperature.

Step 3. For an ideal gas, internal energy depends only on temperature; since TT is unchanged throughout, ΔU=0\Delta U=0 over the entire process. …

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