Q.Explain why the noble gases show very low chemical reactivity in general, and why xenon in particular is able to form a genuine chemistry of compounds.
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Start your 14-day free trial to unlock the full solution →Every noble gas (except helium, with a full shell) has the outer configuration -- a completely filled valence shell. Because chemical bonding is fundamentally driven by atoms gaining, losing or sharing electrons to reach a more stable, complete electron configuration, an atom that already has a complete octet has essentially no inherent tendency either to gain or lose electrons, and consequently very little tendency to form ordinary covalent or ionic bonds -- this is the structural root of the noble gases' celebrated chemical inertness. Xenon, however, is an exception among the practically available noble gases (radon is too radioactive to study conveniently) for two related reasons: it is the largest and most polarisable of the readily available noble gases, so its outermost electrons are held comparatively loosely, and it has the lowest first ionisation enthalpy of the group's stable members. This ionisation enthalpy, though still very high by the standards of the periodic table generally, is low enough that an extremely electronegative, strongly oxidising partner -- above all fluorine, the most electronegative element there is -- can pull sufficien …
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