Q.The magnetic susceptibility of magnesium at 300 K is . At what temperature will its magnetic susceptibility become ?
Concept understanding — Curie's Law
Curie's Law: Why Heat Kills Magnetism
Imagine a room full of tiny compass needles, each free to spin. At room temperature, they jostle around randomly — point every which way, and the net direction is zero. Now walk in carrying a strong bar magnet. The needles feel the tug and try to align with your magnet's field. But thermal jostling fights back, shaking them loose. The stronger the shaking (higher temperature), the harder it is to keep them lined up.
That tug-of-war is the heart of paramagnetism.
The Intuition
A paramagnetic material has atoms with permanent magnetic moments — think of each atom as a tiny bar magnet. Without an external field, thermal energy randomises their directions; net magnetisation is zero. Apply a magnetic field , and each moment wants to align with (lower energy). But temperature supplies random kicks that knock them out of alignment.
Two competing effects:
- Field tries to align them → magnetisation grows with .
- Temperature tries to randomise them → shrinks as rises.
The simplest guess? Magnetisation should be proportional to . That guess is exactly Curie's Law.
The Precise Statement
For a paramagnetic material in a not-too-strong magnetic field, the magnetisation (magnetic moment per unit volume) is
where is the Curie constant (depends on the material — number of magnetic atoms per volume and their individual moment strength). The magnetic susceptibility is defined by , so
This is Curie's Law: susceptibility is inversely proportional to absolute temperature. Double the temperature, halve the susceptibility.
What It Tells You
- At high : thermal chaos wins — the material barely responds to a field ( small).
- At low : alignment becomes easier — grows large.
- It fails when is very strong or is very low (then all moments are nearly aligned, and you can't get more magnetisation — saturation). It also fails if the material orders magnetically (ferromagnetism, antiferromagnetism) below some critical temperature.
Why It Works (Briefly)
A deeper derivation from statistical mechanics shows that for non-interacting magnetic moments, the average alignment is given by the Brillouin function. In the limit of weak field (), that function reduces to a linear form, yielding exactly . The constant comes out as for moments of size .
Curie's Law is the magnetic analogue of the ideal gas law in a sense: both describe a system where particles don't interact, and thermal energy dominates over the aligning/ordering influence.
The Key Takeaway
Curie's Law says: for a paramagnet, . Heat it up, and it becomes less magnetic. Cool it down, and it responds more strongly — until other physics takes over.
Curie's law is a formula-based CBSE Class 12 Physics NCERT topic, commonly searched as Curie's law formula and derivation class 12 or susceptibility temperature relation paramagnetic. This inverse-temperature susceptibility relationship is a dependable short-answer topic in board exams and appears in JEE Main/NEET physics questions on magnetic materials.
Part (a): Curie's law for paramagnetic magnesium gives K. Part (b): is negative, so the material is diamagnetic.
Magnesium is paramagnetic. For a paramagnet the susceptibility varies inversely with absolute temperature (Curie's law):
where is the Curie constant. Writing it for the two states,
Dividing eliminates :
Substituting K, , :
grew by a factor ; since , the temperature must fall by the same factor: K.
.
Concept understanding — Diamagnetism
Diamagnetism: The Quiet Repulsion
Imagine you bring a magnet near a piece of copper or water. Nothing dramatic happens — no strong pull like iron, no noticeable push. But if you had a very sensitive scale, you'd detect a tiny repulsion. The material is pushed away, ever so slightly. That's diamagnetism.
Why does this happen? The key is that in a diamagnetic material, every atom has zero net magnetic moment to begin with. All its electrons are paired up — each electron's tiny magnetic field is cancelled by its partner. The atom is magnetically neutral.
Now bring an external magnetic field. Something subtle occurs: the field slightly distorts the motion of the orbiting electrons. According to Lenz's law, the electrons respond by creating a tiny induced magnetic moment that opposes the applied field. This is like a weak electromagnetic shield — the material generates its own field pointing opposite to the external one.
This induced moment is temporary. Remove the external field, and the material returns to being magnetically neutral. No permanent magnetism remains.
The result? The material is weakly repelled. The strength of this repulsion is measured by magnetic susceptibility , which for diamagnets is small and negative — typically around to .
The Precise Statement
Diamagnetism is the property of materials whose atoms have no permanent magnetic dipole moment. When placed in an external magnetic field , the orbital motion of electrons induces a magnetic moment opposite to , leading to a negative magnetic susceptibility .
where is electron charge, its mass, and the mean square orbital radius.
The susceptibility is:
- Small in magnitude ()
- Negative (repulsion)
- Independent of temperature — because it arises from orbital motion, not from thermal alignment of permanent moments
Unlike paramagnets and ferromagnets, diamagnetism is present in all materials. But it's usually masked by stronger magnetic effects. Only in materials with no unpaired electrons (like copper, bismuth, water, and most organic compounds) does diamagnetism become the dominant response.
Common Examples
| Material | (approx.) | Behaviour |
|---|---|---|
| Bismuth | Strongest diamagnet among elements | |
| Copper | Weakly repelled | |
| Water | Pure water is diamagnetic | |
| Graphite | Anisotropic — stronger along certain axes |
| A common mistake: thinking diamagnets are "non-magnetic". They are magnetic — just very weakly, and in the opposite direction. A diamagnet in a non-uniform field will move toward the weaker field region, not toward the magnet.
Why Temperature Doesn't Matter
In paramagnetism, thermal energy randomises the alignment of permanent atomic moments, so depends on temperature (Curie's law). In diamagnetism, there are no permanent moments to randomise. The induced moment is purely a response to the applied field, arising from the fundamental orbital motion of electrons. Temperature has almost no effect on this — the orbits are fixed by quantum mechanics, not by thermal agitation.
So diamagnetism is universal, weak, temperature-independent, and always repulsive. It's the quiet, ever-present magnetic property that only reveals itself when louder voices are absent.
Diamagnetism is a standard CBSE Class 12 Physics NCERT topic under Magnetism and Matter, frequently searched as diamagnetic materials examples and properties class 12 or why diamagnetism is temperature independent. This concept is regularly paired with paramagnetism and ferromagnetism in comparison-based questions across CBSE boards and JEE Main/NEET physics.
Part (a): Curie's law for paramagnetic magnesium gives K. Part (b): is negative, so the material is diamagnetic.
The sign of the magnetic susceptibility classifies a material:
- , small (–): paramagnetic
- , large: ferromagnetic
- : diamagnetic (magnetised opposite to the field)
Here is negative, so — regardless of its magnitude — the material is diamagnetic. (A magnitude this close to is characteristic of a superconductor, a perfect diamagnet with .)
Do not be misled by the large size of ; only the negative sign matters for identifying diamagnetism.
The material with is diamagnetic.
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