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Q.Draw a plot of α\alpha-particle scattering by a thin foil of gold to show the variation of the number of the scattered particles with scattering angle. Describe briefly how the large angle scattering explains the existence of the nucleus inside the atom. Explain with the help of impact parameter picture, how Rutherford scattering serves a powerful way to determine an upper limit on the size of the nucleus.

CBSECBSE Class XII Board 2019Subjective· 3mImportance★★★★★
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Rutherford’s gold-foil experiment showed that most α\alpha-particles pass through undeflected, but a tiny fraction scatter through large angles — this could only happen if the atom’s positive charge is concentrated in a tiny, massive nucleus. By relating the scattering angle to the impact parameter, the experiment sets an upper limit on nuclear size (about 10−1410^{-14} m).

Graph of the number of scattered alpha particles N versus scattering angle theta (0 to 180 degrees) on a log scale for the Geiger-Marsden experiment, showing data points falling steeply along the N proportional to 1/sin^4(theta/2) curve.
Graph of the number of scattered alpha particles N versus scattering angle theta (0 to 180 degrees) on a log scale for the Geiger-Marsden experiment, showing data points falling steeply along the N proportional to 1/sin^4(theta/2) curve.

The core idea

Before Rutherford, the atom was imagined as a “plum pudding” — positive charge spread uniformly throughout a sphere, with electrons embedded like raisins. If that were true, α\alpha-particles (fast, heavy, positively charged) would barely be deflected as they passed through. But Geiger and Marsden observed that about 1 in 8000 α\alpha-particles bounced back — some through angles greater than 90∘90^\circ. That was impossible with a diffuse charge. The only explanation: the positive charge and most of the mass must be crammed into a region far smaller than the atom itself — the nucleus.


1. The scattering plot

The graph of number NN of scattered α\alpha-particles versus scattering angle θ\theta looks like this:

  • At small θ\theta (say 1∘1^\circ–10∘10^\circ), NN is huge — most particles are barely deflected.
  • As θ\theta increases, NN drops sharply. At θ=90∘\theta = 90^\circ, NN is already very small.
  • Beyond 90∘90^\circ (backscattering), NN is tiny but non-zero — these are the particles that hit the nucleus nearly head-on.

Mathematically, Rutherford derived:

N(θ)∝1sin⁡4(θ/2)N(\theta) \propto \frac{1}{\sin^4(\theta/2)}

So the curve falls off steeply, not linearly. A log‑scale plot would show a straight line for this relation — a powerful experimental check.

Watch out

A common mistake is to think the graph is symmetric about 90∘90^\circ. It is not — the fall from 0∘0^\circ to 90∘90^\circ is far steeper than from 90∘90^\circ to 180∘180^\circ, because sin⁡4(θ/2)\sin^4(\theta/2) changes fastest near θ=0\theta=0.


2. How large‑angle scattering proves the nucleus exists

Imagine firing a bullet at a sheet of tissue paper. If the bullet bounces straight back, there must be something hard behind the paper. Similarly:

  • A small deflection (θ\theta small) means the α\alpha-particle passed far from any concentrated charge — it felt only a weak Coulomb repulsion from the whole atom.
  • A large deflection (θ\theta near 180∘180^\circ) means the α\alpha-particle came very close to a massive, positively charged core — so close that the repulsive force was enormous, reversing its direction.

If the positive charge were spread out, the force at any point inside the atom would be too weak to reverse a fast α\alpha-particle. Only a point‑like (or very tiny) nucleus can produce the huge electric field needed for backscattering.

Important

The existence of any α\alpha-particle scattered through θ>90∘\theta > 90^\circ is direct evidence that the atom contains a dense, positively charged nucleus — because a diffuse charge cannot produce such a large repulsive force.


3. The impact parameter picture and nuclear size

The impact parameter bb is the perpendicular distance between the initial velocity vector of the α\alpha-particle and the centre of the nucleus. It determines the scattering angle:

  • Large bb → particle passes far from nucleus → small θ\theta.
  • Small bb → particle passes close to nucleus → large θ\theta.
  • b=0b = 0 → head‑on collision → θ=180∘\theta = 180^\circ (direct backscatter).

Rutherford derived the exact relation:

b=Ze24πϵ0⋅cot⁡(θ/2)Eb = \frac{Z e^2}{4 \pi \epsilon_0} \cdot \frac{\cot(\theta/2)}{E}

where ZZ is the atomic number of the target, ee the elementary charge, and EE the kinetic energy of the α\alpha-particle. …

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