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Q.A photon emitted during the de-excitation of electron from a state nn to the first excited state in a hydrogen atom, irradiates a metallic cathode of work function 2 eV, in a photo cell, with a stopping potential of 0⋅550\cdot55 V. Obtain the value of the quantum number of the state nn.

(OR)
A hydrogen atom in the ground state is excited by an electron beam of 12⋅512\cdot5 eV energy. Find out the maximum number of lines emitted by the atom from its excited state.
CBSECBSE Class XII Board 2019Subjective· 2mImportance★★★★★
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  1. The photocell fixes the photon energy at 2.552.55 eV; matching it to a hydrogen n→2n\to2 transition gives n=4n=4.
  2. A 12.512.5 eV electron beam raises ground-state hydrogen only to n=3n=3, so a maximum of 33 spectral lines are emitted.

Part (a)

The stopping potential gives the maximum kinetic energy of the photoelectrons, Kmax⁡=eVs=0.55K_{\max}=eV_s=0.55 eV. By Einstein's equation the incident photon energy is

Eγ=ϕ+Kmax⁡=2+0.55=2.55 eV.E_\gamma=\phi+K_{\max}=2+0.55=2.55\ \text{eV}.

This photon was emitted in a hydrogen de-excitation from level nn to the first excited state n=2n=2. Using En=−13.6n2E_n=-\dfrac{13.6}{n^2} eV,

Eγ=En−E2=−13.6n2+13.64=2.55.E_\gamma=E_n-E_2=-\frac{13.6}{n^2}+\frac{13.6}{4}=2.55.

Since 13.64=3.4\dfrac{13.6}{4}=3.4,

3.4−13.6n2=2.55⇒13.6n2=0.85⇒n2=13.60.85=16⇒n=4.3.4-\frac{13.6}{n^2}=2.55\Rightarrow\frac{13.6}{n^2}=0.85\Rightarrow n^2=\frac{13.6}{0.85}=16\Rightarrow n=4. …

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