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Q.The maximum kinetic energy of the photoelectrons emitted is doubled when the wavelength of light incident on the photosensitive surface changes from λ1\lambda_1 to λ2\lambda_2. Deduce expressions for the threshold wavelength and work function for the metal surface in terms of λ1\lambda_1 and λ2\lambda_2.

CBSECBSE Class XII Board 2020Subjective· 3mImportance★★★★★
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Using Einstein’s photoelectric equation, the condition that maximum kinetic energy doubles when wavelength changes from λ1\lambda_1 to λ2\lambda_2 gives two equations. Solving them yields the threshold wavelength λ0=λ1λ22λ2−λ1\lambda_0 = \frac{\lambda_1 \lambda_2}{2\lambda_2 - \lambda_1} and the work function ϕ=hcλ0\phi = \frac{hc}{\lambda_0}.

Concept and Intuition

The photoelectric effect is governed by Einstein’s equation:

Kmax=hcλ−ϕK_{\text{max}} = \frac{hc}{\lambda} - \phi

where KmaxK_{\text{max}} is the maximum kinetic energy of emitted electrons, hc/λhc/\lambda is the energy of the incident photon, and ϕ\phi is the work function of the metal (the minimum energy needed to eject an electron). The threshold wavelength λ0\lambda_0 is related to the work function by ϕ=hc/λ0\phi = hc/\lambda_0.

The problem tells us that when the wavelength changes from λ1\lambda_1 to λ2\lambda_2, the maximum kinetic energy doubles. This is a direct relation between two states of the same metal. We don’t know the actual values of KmaxK_{\text{max}} or ϕ\phi, but we can set up two equations and eliminate the unknown KmaxK_{\text{max}} to find λ0\lambda_0 and ϕ\phi in terms of λ1\lambda_1 and λ2\lambda_2.

Watch out

A common mistake is to assume that doubling the photon energy doubles the kinetic energy. That is false — the work function is a constant subtraction, so the relationship is not proportional. Always write the full equation.

Step-by-Step Solution

1. Write the photoelectric equation for the first wavelength λ1\lambda_1.

Let the maximum kinetic energy at λ1\lambda_1 be KK. Then:

K=hcλ1−ϕ(1)K = \frac{hc}{\lambda_1} - \phi \qquad(1)

2. Write the equation for the second wavelength λ2\lambda_2.

The kinetic energy is doubled, so it is 2K2K:

2K=hcλ2−ϕ(2)2K = \frac{hc}{\lambda_2} - \phi \qquad(2)

3. Eliminate KK to get a relation between λ1\lambda_1, λ2\lambda_2, and ϕ\phi.

From (1), K=hcλ1−ϕK = \frac{hc}{\lambda_1} - \phi. Substitute into (2):

2(hcλ1−ϕ)=hcλ2−ϕ2\left(\frac{hc}{\lambda_1} - \phi\right) = \frac{hc}{\lambda_2} - \phi

Expand:

2hcλ1−2ϕ=hcλ2−ϕ\frac{2hc}{\lambda_1} - 2\phi = \frac{hc}{\lambda_2} - \phi

Bring terms involving ϕ\phi together:

2hcλ1−hcλ2=2ϕ−ϕ=ϕ\frac{2hc}{\lambda_1} - \frac{hc}{\lambda_2} = 2\phi - \phi = \phi

So:

ϕ=hc(2λ1−1λ2)(3)\phi = hc\left(\frac{2}{\lambda_1} - \frac{1}{\lambda_2}\right) \qquad(3)

4. Express the work function in terms of threshold wavelength.

By definition, ϕ=hcλ0\phi = \frac{hc}{\lambda_0}. Equate with (3):

hcλ0=hc(2λ1−1λ2)\frac{hc}{\lambda_0} = hc\left(\frac{2}{\lambda_1} - \frac{1}{\lambda_2}\right)

Cancel hchc (non-zero):

1λ0=2λ1−1λ2\frac{1}{\lambda_0} = \frac{2}{\lambda_1} - \frac{1}{\lambda_2}

5. Solve for λ0\lambda_0.

Take the reciprocal after combining the right-hand side:

1λ0=2λ2−λ1λ1λ2\frac{1}{\lambda_0} = \frac{2\lambda_2 - \lambda_1}{\lambda_1 \lambda_2}

Thus: …

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