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Q.When the terminals of a cell are connected to a conductor of resistance R, an electric current flows through the circuit. The electrolyte of the cell also offers some resistance in the path of the current, like the conductor. This resistance offered by the electrolyte is called internal resistance of the cell (r). It depends upon the nature of the electrolyte, the area of the electrodes immersed in the electrolyte and the temperature. Due to internal resistance, a part of the energy supplied by the cell is wasted in the form of heat. When no current is drawn from the cell, the potential difference between the two electrodes is known as emf of the cell (ε\varepsilon). With a current drawn from the cell, the potential difference between the two electrodes is termed as terminal potential difference (V).

(i) Choose the incorrect statement : (A) The potential difference (V) between the two terminals of a cell in a closed circuit is always less than its emf (ε\varepsilon), during discharge of the cell. (B) The internal resistance of a cell decreases with the decrease in temperature of the electrolyte. (C) When current is drawn from the cell then V=ε−IrV = \varepsilon - Ir. (D) The graph between potential difference between the two terminals of the cell (V) and the current (I) through it is a straight line with a negative slope.
(ii) Two cells of emfs 2⋅02{\cdot}0 V and 6⋅06{\cdot}0 V and internal resistances 0⋅1 Ω0{\cdot}1\ \Omega and 0⋅4 Ω0{\cdot}4\ \Omega respectively, are connected in parallel. The equivalent emf of the combination will be : (A) 2⋅02{\cdot}0 V (B) 2⋅82{\cdot}8 V (C) 6⋅06{\cdot}0 V (D) 8⋅08{\cdot}0 V
(iii) Dipped in the solution, the electrode exchanges charges with the electrolyte. The positive electrode develops a potential V+V_+ (V+>0V_+ > 0), and the negative electrode develops a potential −(V−)-(V_-) (V−≥0V_- \geq 0), relative to the electrolyte adjacent to it. When no current is drawn from the cell then : (A) ε=V++V−>0\varepsilon = V_+ + V_- > 0 (B) ε=V+−V−>0\varepsilon = V_+ - V_- > 0 (C) ε=V++V−<0\varepsilon = V_+ + V_- < 0 (D) ε=V++V−=0\varepsilon = V_+ + V_- = 0
(iv)
(a) Five identical cells, each of emf 2 V and internal resistance 0⋅1 Ω0{\cdot}1\ \Omega are connected in parallel. This combination in turn is connected to an external resistor of 9⋅98 Ω9{\cdot}98\ \Omega. The current flowing through the resistor is : (A) 0⋅050{\cdot}05 A (B) 0⋅10{\cdot}1 A (C) 0⋅150{\cdot}15 A (D) 0⋅20{\cdot}2 A
(OR)
(b) Potential difference across a cell in the open circuit is 6 V. It becomes 4 V when a current of 2 A is drawn from it. The internal resistance of the cell is : (A) 1⋅0 Ω1{\cdot}0\ \Omega (B) 1⋅5 Ω1{\cdot}5\ \Omega (C) 2⋅0 Ω2{\cdot}0\ \Omega (D) 2⋅5 Ω2{\cdot}5\ \Omega
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Internal resistance makes V=ε−Ir<εV=\varepsilon-Ir<\varepsilon when current flows. Answers: (i) B, (ii) B (2.8 V), (iii) A, (iv)(a) 0.2 A → D, (iv)(b) 1.0 Ω → A.

The electrolyte of a cell opposes the current just like the external resistor, so a part IrIr of the emf is lost inside the cell. The voltage actually available at the terminals is therefore V=ε−IrV=\varepsilon-Ir.

Part (a)

(i) Which statement is incorrect?

  • (A) During discharge V=ε−Ir<εV=\varepsilon-Ir<\varepsilon — correct.
  • (B) "Internal resistance decreases as temperature decreases." As temperature falls, ion mobility falls, so internal resistance rises. This statement is false — it is the required answer.
  • (C) V=ε−IrV=\varepsilon-Ir — the standard relation, correct.
  • (D) V=ε−IrV=\varepsilon-Ir is linear in II with slope −r-r, a straight line of negative slope — correct.
Watch out

The trap is (B): colder electrolyte ⇒\Rightarrow higher internal resistance, not lower.

(ii) Equivalent emf of two parallel cells.

For cells in parallel the equivalent emf is the conductance-weighted mean:

εeq=ε1/r1+ε2/r21/r1+1/r2.\varepsilon_{eq}=\frac{\varepsilon_1/r_1+\varepsilon_2/r_2}{1/r_1+1/r_2}.

With ε1=2.0 V, r1=0.1 Ω, ε2=6.0 V, r2=0.4 Ω\varepsilon_1=2.0\ \text{V},\ r_1=0.1\ \Omega,\ \varepsilon_2=6.0\ \text{V},\ r_2=0.4\ \Omega:

εeq=20+1510+2.5=3512.5=2.8 V⇒ (B).\varepsilon_{eq}=\frac{20+15}{10+2.5}=\frac{35}{12.5}=2.8\ \text{V}\quad\Rightarrow\ \textbf{(B)}.

(iii) EMF from electrode potentials.

The positive electrode sits at +V++V_+ and the negative at −V−-V_- relative to the electrolyte, so

ε=V+−(−V−)=V++V−>0⇒ (A).\varepsilon=V_+-(-V_-)=V_++V_->0\quad\Rightarrow\ \textbf{(A)}.

(iv)(a) Five identical cells in parallel feeding 9.98 Ω9.98\ \Omega.

Identical cells in parallel keep the same emf but divide the internal resistance: …

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