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Q.The work function for a photosensitive surface is 3⋅3153{\cdot}315 eV. The cut-off wavelength for photoemission of electrons from this surface is : (A) 150 nm (B) 200 nm (C) 375 nm (D) 500 nm

CBSECBSE Class XII Board 2024MCQ· 1mImportance★★★★★
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The cut-off wavelength is the longest wavelength that can eject electrons, found by equating the photon energy to the work function. Using λcut-off=hcϕ\lambda_{\text{cut-off}} = \frac{hc}{\phi}, with ϕ=3.315\phi = 3.315 eV, we get λ=375\lambda = 375 nm, which corresponds to option (C).

The key idea here is the photoelectric effect: a photon must have at least as much energy as the work function (ϕ\phi) to eject an electron. The cut-off wavelength is the threshold — any longer wavelength means the photon’s energy is too low. So we simply set the photon energy E=hcλE = \frac{hc}{\lambda} equal to ϕ\phi and solve for λ\lambda.

A common pitfall is forgetting to convert units properly. The work function is given in eV, but hh and cc are usually in SI units (joules and meters). You must either convert eV to joules or use the handy constant hc=1240hc = 1240 eV·nm.

Watch out

If you use h=6.63×10−34h = 6.63 \times 10^{-34} J·s and c=3×108c = 3 \times 10^8 m/s, remember to convert 3.315 eV to joules: 1 eV=1.6×10−191 \text{ eV} = 1.6 \times 10^{-19} J. A small arithmetic slip here can give a wrong answer.

Let’s work through it step by step.

  1. Recall the photoelectric equation. The minimum photon energy needed to just eject an electron is E=ϕE = \phi. For a photon, E=hcλE = \frac{hc}{\lambda}. So:

hcλcut-off=ϕ\frac{hc}{\lambda_{\text{cut-off}}} = \phi

Rearranging:

λcut-off=hcϕ\lambda_{\text{cut-off}} = \frac{hc}{\phi}

  1. Choose a convenient form of hchc. Since the answer choices are in nanometres and ϕ\phi is in eV, use the standard value: hc=1240 eV⋅nmhc = 1240 \text{ eV·nm} …

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