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Answer in brief · Q2

Q.On what factors do the degrees of freedom depend?

Maharashtra MsbshseTextbookSubjectiveImportance★★★★★
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The degrees of freedom of a molecule are the number of independent coordinates needed to fully specify its position and configuration. For a single point-mass molecule (monatomic gas), this is just 3 translational degrees of freedom. For a diatomic molecule, 2 additional rotational degrees of freedom become available (rotation about the two axes perpendicular to the bond), and if the molecule is treated as non-rigid, further vibrational degrees of freedom appear. For polyatomic molecules, the number of rotational degrees of freedom depends on whether the molecule is linear (2 rotational dof, like a diatomic) or non-linear (3 rotational dof, since it can rotate about three mutually perpendicular axes), and the number of vibrational modes depends on the specific geometric arrangement of its atoms. So degrees of freedom depend on: (i) the number of atoms in the molecule, (ii) its geometric shape (linear vs non-linear), and (iii) whether internal vibrations are allowed. [!ANSWER] Degrees of freedom depend on the number of atoms in the molecule, its geometric structure (linear or non-linear), and whether vibrational motion is allowed.

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