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Questions 3-25 · Q18

Q.Calculate the average molecular kinetic energy

(i) per kmol
(ii) per kg
(iii) per molecule of oxygen at 127 ºC, given that the molecular weight of oxygen is 32, R is 8.31 J mol⁻¹ K⁻¹ and Avogadro's number NAN_A is 6.02×10236.02\times10^{23} molecules mol⁻¹.
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The average kinetic energy per mole of gas is E = (3/2)RT. At T = 127 ºC = 400 K, with R = 8.31 J mol⁻¹K⁻¹: E(per mole) = 1.5 × 8.31 × 400 = 4986 J/mol.

  1. PER KMOL: since 1 kmol = 1000 mol, E(per kmol) = 4986 × 1000 = 4.986×10^6 J, matching the textbook's printed answer exactly.
  2. PER KG: the molar mass of O2 is 32 g/mol = 0.032 kg/mol, so the number of moles in 1 kg is 1/0.032 = 31.25 mol. E(per kg) = 31.25 × 4986 = 155,812.5 J/kg ≈ 1.558×10^5 J/kg. Note: the textbook's own printed answer states this as '1.558×10² J', which appears to have lost several orders of magnitude in typesetting (consistent with other exponent/superscript corruption seen throughout this scanned chapter) -- the value computed directly and independently here, 1.558×10^5 J/kg, is the value consistent with both the per-kmol and per …

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