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Questions 3-25 · Q16

Q.Compare the rms speed of hydrogen molecules at 127 ºC with the rms speed of oxygen molecules at 27 ºC, given that the molecular masses of hydrogen and oxygen are 2 and 32 respectively.

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Using v_rms = sqrt(3RT/M0), the ratio of rms speeds is v_rms(H2)/v_rms(O2) = sqrt[(T_H2/M_H2)/(T_O2/M_O2)]. Converting temperatures to Kelvin: T_H2 = 127 + 273 = 400 K, T_O2 = 27 + 273 = 300 K. Substituting M_H2 = 2, M_O2 = 32: ratio = sqrt[(400/2)/(300/32)] = sqrt[200/9.375] = sqrt(21.333) ≈ 4.619. Expressing this as an exact ratio: sqrt(200/9.375) = sqrt(200 × 32/300) = sqrt(6 …

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