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Questions 3-25 · Q4

Q.Explain, on the basis of kinetic theory, how the pressure of a gas changes if its volume is reduced at constant temperature.

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From kinetic theory, the pressure of an ideal gas is P = (1/3)(N/V) m <v^2>, where N/V is the number of molecules per unit volume (the number density) and <v^2> is the mean square molecular speed. At constant temperature, the mean square speed <v^2> stays unchanged (since it depends only on T for a given gas, via <v^2> = 3kBT/m). If the volume V is reduced while the number of molecules N stays fixed, the number density N/V increases -- the same molecules are now confined to a smaller space. With more molecules in a given volume, molecules strike each unit area of the container walls more frequently in a given time, which directly increases the pressure. Since P is inversely proportional to V at fixed N and T (P ∝ 1/V, i.e. Boyle's law), reducing the volume increases the pressure in exact inverse proportion. [!ANSWER] Reducing the volume at constant temperature increases the number density of molecules, so they collide with the walls more frequently, and the pressure increases -- consistent with P ∝ 1/V from kinetic theory.

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