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Q.A hydrogen atom consists of an electron revolving in a circular orbit of radius rr with a certain velocity vv around a proton located at the nucleus. The electrostatic force of attraction between the revolving electron and the proton provides the requisite centripetal force to keep it in certain stable orbits. The angular momentum of the electron in these orbits is some integral multiple of h2π\frac{h}{2\pi}. When an electron makes a transition from one orbit of higher energy to that of lower energy, a photon is emitted having energy equal to the difference between the energies of the initial and final states. Assuming the mass and charge of the electron as mm and −e-e respectively, answer the following questions. (Take K=14πε0K = \frac{1}{4\pi\varepsilon_0}.)

(i) The expression for the speed of the electron vv in terms of the radius of the orbit (r)(r) and the physical constant KK is:
(ii) The total energy of the atom in terms of rr and the physical constant KK is:
(iii) A photon of wavelength 500500 nm is emitted when an electron makes a transition from one state to another state in an atom. The change in the total energy of the electron and the change in its kinetic energy (in eV) are: (A) 2.48, −2.482.48,\ -2.48 (B) 1.24, 1.241.24,\ 1.24 (C) −2.48, 2.48-2.48,\ 2.48 (D) 1.24, −1.241.24,\ -1.24 (iv)(a) The frequency of revolution of the electron in its nthn^{th} orbit is proportional to: (A) nn (B) 1n\frac{1}{n} (C) 1n2\frac{1}{n^2} (D) 1n3\frac{1}{n^3}
(OR)
(iv)(b) An electron makes a transition from the −3.4-3.4 eV state to the ground state in a hydrogen atom. Its radius of orbit changes by: (radius of orbit of electron in the ground state =0.53= 0.53 Å) (A) 0.530.53 Å (B) 1.061.06 Å (C) 1.591.59 Å (D) 2.122.12 Å
CBSECBSE Class XII Board 2025Subjective· 4mImportance★★★★★
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(i) v=Ke2mrv=\sqrt{\dfrac{Ke^2}{mr}}; (ii) E=−Ke22rE=-\dfrac{Ke^2}{2r}; (iii) (C) −2.48, 2.48-2.48,\ 2.48; (iv)(a) (D) f∝1/n3f\propto 1/n^3; (iv)(b) (C) Δr=1.59 A˚\Delta r=1.59\ \text{Å}.

Part (a)

  1. Speed of the electron. The Coulomb attraction supplies the centripetal force:

    Ke2r2=mv2r⇒v2=Ke2mr⇒v=Ke2mr.\frac{Ke^2}{r^2}=\frac{mv^2}{r}\Rightarrow v^2=\frac{Ke^2}{mr}\Rightarrow v=\sqrt{\frac{Ke^2}{mr}}.

  2. Total energy.

    KE=12mv2=Ke22r,PE=−Ke2r,KE=\tfrac12 mv^2=\frac{Ke^2}{2r},\qquad PE=-\frac{Ke^2}{r},

    E=KE+PE=Ke22r−Ke2r=−Ke22r.E=KE+PE=\frac{Ke^2}{2r}-\frac{Ke^2}{r}=-\frac{Ke^2}{2r}.

    The negative sign shows the electron is bound; note KE=−EKE=-E. (iii) Photon of 500 nm500\ \text{nm}. Using hc=1240 eV nmhc=1240\ \text{eV nm},

    Ephoton=1240500=2.48 eV.E_{\text{photon}}=\frac{1240}{500}=2.48\ \text{eV}.

    On emission the atom's total energy drops: ΔEtotal=−2.48 eV\Delta E_{\text{total}}=-2.48\ \text{eV}. Since KE=−EKE=-E, a fall in total energy means a rise in kinetic energy of the same magnitude: ΔKE=+2.48 eV\Delta KE=+2.48\ \text{eV}. Option (C). (iv)(a) Frequency of revolution. From Bohr's model r∝n2r\propto n^2 and v∝1/nv\propto 1/n, so f=v2πr∝1/nn2=1n3.f=\frac{v}{2\pi r}\propto\frac{1/n}{n^2}=\frac{1}{n^3}. …

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