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Biology · Ch 7 — Plant Growth and Mineral Nutrition

Nitrogen Fixation

Nitrogen Fixation

Nitrogen fixation : The atmosphere is the source of nitrogen, but it cannot be used directly - it combines with C, H, N and O to form compounds before being used. The conversion of the free nitrogen (N2) of the atmosphere into nitrogenous salts, making it available to plants, is called nitrogen fixation. It is of two types, physical and biological fixation.

Note

Physical and industrial nitrogen fixation

Physical Nitrogen fixation : It occurs in several steps and starts with the combination of atmospheric nitrogen with oxygen under the influence of electric discharge and thunderstorms, producing nitric oxide:

N2 + O2 --(electric discharge / thunderstorm)--> 2NO (nitric oxide)

The nitric oxide is then oxidised to nitrogen peroxide in the presence of oxygen:

2NO + O2 --(oxidation)--> 2NO2 (nitrogen peroxide)

During rains the nitrogen peroxide combines with rain water to form nitrous acid and nitric acid, which come to the ground with the rain:

2NO2 + rain water --> HNO2 (nitrous acid) + HNO3 (nitric acid)

On the ground the alkali radicals of the soil react with nitric acid to produce nitrites and nitrates, the absorbable form:

HNO3 + Ca or K salts --> Ca or K nitrates

Industrial nitrogen fixation : It occurs by the Haber-Bosch process at high temperature and pressure:

N2 + 3H2 --(450 °C, 200 atm)--> 2NH3 (ammonia)

Ammonia is then converted to urea, as urea is less toxic.

Tip

Internet my friend

Enlist the names of symbiotic and free-living nitrogen-fixing bacteria.

Remember

Always Remember

Today nearly 80 % of the nitrogen found in human tissues originates from the Haber-Bosch process. …