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Question 79 of 90

Q.Derive an expression for a pressure exerted by a gas on the basis of kinetic theory of gases.

Maharashtra MsbshseMaharashtra HSC (MSBSHSE) Board 2022Subjective· 4mImportance★★★★★
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Sum the momentum transferred per collision over all molecules hitting a wall, per unit time and area, to get the pressure.

Consider NN gas molecules of mass mm each in a cubical container of side LL (volume V=L3V=L^3). Consider one molecule moving with velocity component cxc_x perpendicular to a wall. On elastic collision with the wall, its momentum change is 2mcx2mc_x. It returns to hit the same wall after time 2L/cx2L/c_x, so the average force it exerts on that wall is 2mcx2L/cx=mcx2L\dfrac{2mc_x}{2L/c_x} = \dfrac{mc_x^2}{L}.

Summing over all NN molecules, the total force on the wall is mL∑cx2=Nm⟨cx2⟩L\dfrac{m}{L}\sum c_x^2 = \dfrac{Nm\langle c_x^2\rangle}{L}. Pressure = force/area:

P=Nm⟨cx2⟩L⋅L2=Nm⟨cx2⟩VP = \frac{Nm\langle c_x^2\rangle}{L\cdot L^2} = \frac{Nm\langle c_x^2\rangle}{V} …

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