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Q.When a given photosensitive material is irradiated with light of frequency ν\nu, the maximum speed of the emitted photoelectrons equals VmaxV_{max}. The graph shown in the figure gives a plot of Vmax2V_{max}^2 varying with frequency ν\nu. Obtain an expression for

(a) Planck's constant, and
(b) The work function of the given photosensitive material in terms of the parameters 'l', 'n' and the mass 'm' of the electron.
(c) How is threshold frequency determined from the plot?
Figure — CBSE 2019 55/5/1 Q20
Figure
CBSECBSE Class XII Board 2019Subjective· 3mImportance★★★★★
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Einstein’s photoelectric equation gives a linear relation between Vmax2V_{max}^2 and ν\nu. The slope and intercepts of the graph directly yield Planck’s constant h=ml2nh = \frac{ml}{2n}, work function ϕ0=ml2\phi_0 = \frac{ml}{2}, and threshold frequency ν0=n\nu_0 = n.

Figure — CBSE 2019 55/5/1 Q20
Figure — CBSE 2019 55/5/1 Q20

The photoelectric effect is one of those rare experiments where a single equation — Einstein’s — explains an entire straight-line graph. The key insight is that the maximum kinetic energy of ejected electrons, 12mVmax2\frac{1}{2} m V_{max}^2, is linearly related to the frequency of incident light. That linearity is what makes the graph (shown above) a straight line, and every feature of that line (slope, intercepts) carries physical meaning.

Let’s start from Einstein’s photoelectric equation:

Kmax=12mVmax2=hν−ϕ0K_{max} = \frac{1}{2} m V_{max}^2 = h\nu - \phi_0

Here hh is Planck’s constant, ϕ0\phi_0 the work function of the material, mm the electron mass, and ν\nu the frequency of incident light. Rearranging to match the graph’s axes:

Vmax2=2hmν−2ϕ0mV_{max}^2 = \frac{2h}{m}\nu - \frac{2\phi_0}{m}

This is of the form y=(slope)x+(intercept)y = \text{(slope)}x + \text{(intercept)}, where y=Vmax2y = V_{max}^2 and x=νx = \nu. So the graph is a straight line with:

  • Slope =2hm= \dfrac{2h}{m}
  • yy-intercept (on Vmax2V_{max}^2 axis) =−2ϕ0m= -\dfrac{2\phi_0}{m}
  • xx-intercept (on ν\nu axis) =ϕ0h= \dfrac{\phi_0}{h} — this is the threshold frequency ν0\nu_0, where Vmax2=0V_{max}^2 = 0.

Now, reading the graph's own labelled intercepts, given in terms of the parameters ll and nn:

  1. Identify the yy-intercept: The line cuts the Vmax2V_{max}^2 axis at a point labelled ll. But careful — the intercept is negative (since Vmax2V_{max}^2 becomes zero at a positive ν\nu and negative below threshold). The magnitude is ll, so the actual intercept is −l-l. Hence:

−2ϕ0m=−l⇒ϕ0=ml2-\frac{2\phi_0}{m} = -l \quad\Rightarrow\quad \phi_0 = \frac{ml}{2}

  1. Identify the xx-intercept: The line cuts the ν\nu axis at nn. This is the threshold frequency ν0\nu_0:

ν0=n\nu_0 = n

  1. Find the slope from the intercepts: The slope is rise over run. From the yy-intercept (0,−l)(0, -l) to the xx-intercept (n,0)(n, 0): slope=0−(−l)n−0=ln\text{slope} = \frac{0 - (-l)}{n - 0} = \frac{l}{n} …

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