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Q.Define the terms

(a) threshold frequency, and
(b) stopping potential. How were these terms incorporated in Einstein's photoelectric equation ?
CBSECBSE Class XII Board 2020Subjective· 2mImportance★★★★★
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The photoelectric effect is explained by Einstein's particle theory of light, where threshold frequency is the minimum frequency needed to eject an electron, and stopping potential is the voltage that just stops the most energetic photoelectrons. Einstein's equation Kmax=hf−ϕK_{\text{max}} = hf - \phi directly incorporates both: ϕ=hf0\phi = h f_0 defines the threshold, and eV0=KmaxeV_0 = K_{\text{max}} links stopping potential to the equation.

The Core Idea: Why Light Acts Like a Particle

Before Einstein, physicists thought light was purely a wave. But the photoelectric effect — where light shining on a metal ejects electrons — refused to fit that picture. If light were a wave, a brighter beam (more energy) should eventually kick out electrons, no matter the colour. Instead, experiments showed that for each metal, there's a minimum frequency below which no electrons come out, no matter how bright the light. And the electrons' kinetic energy depended only on frequency, not intensity.

Einstein's revolutionary insight was to treat light as a stream of discrete energy packets — photons — each carrying energy E=hfE = hf, where hh is Planck's constant and ff is the frequency. An electron inside the metal needs a certain minimum energy just to break free — this is the work function, ϕ\phi. If a photon's energy is less than ϕ\phi, no electron can escape, regardless of how many photons hit the surface. Any extra energy above ϕ\phi becomes the electron's kinetic energy.

This is the conceptual backbone. Now let's define the two terms precisely and see how they fit into Einstein's equation.


1. Threshold Frequency (f0f_0)

Definition: The threshold frequency is the minimum frequency of incident light required to just eject an electron from a given metal surface. At this frequency, the photon's energy exactly equals the work function of the metal, so the ejected electron has zero kinetic energy.

Why it exists: Every metal has a characteristic work function ϕ\phi — the energy needed to remove the least tightly bound electron. Since a photon's energy is hfhf, the condition for ejection is hf≥ϕhf \ge \phi. The equality gives the threshold:

f0=ϕhf_0 = \frac{\phi}{h}

If f<f0f < f_0, no photoelectrons are emitted, no matter how intense the light. This was the puzzle that wave theory couldn't solve.


2. Stopping Potential (V0V_0)

Definition: The stopping potential is the minimum reverse voltage (applied between the emitter and collector) that reduces the photoelectric current to zero. It is a measure of the maximum kinetic energy of the ejected electrons.

How it works: When you apply a reverse voltage, you create an electric field that opposes the motion of electrons. The most energetic electrons — those with maximum kinetic energy KmaxK_{\text{max}} — are the hardest to stop. The stopping potential V0V_0 is the voltage that just barely stops these fastest electrons. The work done by the electric field in stopping them is eV0eV_0 (where ee is the electron charge), and this equals their initial kinetic energy:

Kmax=eV0K_{\text{max}} = eV_0

So by measuring V0V_0, you directly measure the maximum kinetic energy of photoelectrons.

Watch out

A common mistake is to think V0V_0 stops all electrons. It actually stops only the most energetic ones. At V=V0V = V_0, the current is zero because even the fastest electron can't reach the collector. Slower electrons are stopped at lower voltages.


3. Einstein's Photoelectric Equation

Einstein combined these ideas into a single, elegant equation. The energy conservation for a single electron-photon interaction is:

hf=ϕ+Kmaxhf = \phi + K_{\text{max}}

The photon's energy hfhf is used in two ways: part of it (ϕ\phi) overcomes the binding energy to free the electron, and the remainder appears as the electron's maximum kinetic energy.

Now, here's how the two terms are incorporated:

  • Threshold frequency: Set Kmax=0K_{\text{max}} = 0 in Einstein's equation. Then hf0=ϕhf_0 = \phi, so f0=ϕ/hf_0 = \phi/h. This defines the threshold directly from the work function. The equation tells you that if f<f0f < f_0, the right-hand side would be negative — impossible — so no emission occurs. …

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