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Question

Q.The radius of the nthn^{\text{th}} orbit in Bohr model of hydrogen atom is proportional to :

(a) 1n2\dfrac{1}{n^2}
(b) 1n\dfrac{1}{n}
(c) n2n^2
(d) nn
CBSECBSE Class XII Board 2023MCQ· 1mImportance★★★★★
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In the Bohr model, the electron's orbit radius grows with the principal quantum number because higher orbits require more angular momentum and lower electrostatic attraction. The radius is proportional to n2n^2.

The Bohr model treats the hydrogen atom as a miniature solar system where the electron orbits the nucleus in circular paths. But unlike planets, the electron can only occupy certain allowed orbits, determined by quantum conditions. The question asks how the orbital radius scales with the quantum number nn.

The key insight is that two forces govern the electron's motion: the electrostatic attraction pulling it inward and the requirement that its angular momentum be quantized. Let me show you how these constraints lead to the radius formula.

The physics behind the orbit

For a stable circular orbit, the centripetal force must equal the electrostatic force:

mv2r=ke2r2\frac{mv^2}{r} = \frac{ke^2}{r^2}

where mm is the electron mass, vv its speed, kk is Coulomb's constant, and ee the electron charge. This gives us one equation relating rr and vv.

Bohr's quantum condition provides the second equation. He postulated that angular momentum is quantized:

mvr=nℏmvr = n\hbar

where ℏ=h2π\hbar = \frac{h}{2\pi} and n=1,2,3,…n = 1, 2, 3, \ldots is the principal quantum number.

Deriving the radius dependence

  1. From the angular momentum condition, solve for vv:

v=nℏmrv = \frac{n\hbar}{mr}

  1. Substitute this into the force balance equation:

mr(nℏmr)2=ke2r2\frac{m}{r}\left(\frac{n\hbar}{mr}\right)^2 = \frac{ke^2}{r^2}

  1. Simplify the left side:

m⋅n2ℏ2m2r3=n2ℏ2mr3=ke2r2\frac{m \cdot n^2\hbar^2}{m^2r^3} = \frac{n^2\hbar^2}{mr^3} = \frac{ke^2}{r^2}

  1. Multiply both sides by r3r^3:

n2ℏ2m=ke2r\frac{n^2\hbar^2}{m} = ke^2 r

  1. Solve for rr: r=n2ℏ2mke2r = \frac{n^2\hbar^2}{mke^2} …

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