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Q.Briefly explain the Geiger-Marsden experiment. Show the variation of the number of particles scattered (N) with scattering angle (θ\theta) in this experiment. What is the main conclusion that can be inferred from this plot ?

CBSECBSE Class XII Board 2023Subjective· 3mImportance★★★★★
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The Geiger-Marsden experiment fired alpha particles at thin gold foil and measured scattering angles. The number of scattered particles varies as N∝1sin⁡4(θ/2)N \propto \frac{1}{\sin^4(\theta/2)}, revealing that atoms contain a tiny, dense, positively charged nucleus.

The Experiment

In 1909, under Rutherford's direction, Hans Geiger and Ernest Marsden bombarded a thin gold foil (about 400 atoms thick) with a beam of alpha particles from a radioactive source. The experimental setup was elegantly simple: alpha particles passed through a collimating slit, struck the foil, and scattered particles were detected by observing scintillations on a zinc sulfide screen that could be moved to different angles.

The expectation, based on J.J. Thomson's "plum pudding" model (where positive charge was spread uniformly throughout the atom with electrons embedded within), was that alpha particles would pass through with only minor deflections—perhaps a degree or two at most. The diffuse positive charge couldn't exert a strong enough force to cause large-angle scattering.

What they observed was shocking: while most alpha particles did pass straight through or deflected by small angles, a tiny fraction (about 1 in 8000) scattered through angles greater than 90°, some even bouncing almost straight back. Rutherford famously remarked it was "as if you fired a 15-inch shell at a piece of tissue paper and it came back and hit you."

The Scattering Law

Rutherford's theoretical analysis, treating the scattering as a Coulomb interaction between the alpha particle (charge +2e+2e) and a concentrated positive charge (the nucleus), led to a precise prediction. The number of alpha particles NN detected at a scattering angle θ\theta follows:

N(θ)∝1sin⁡4(θ/2)N(\theta) \propto \frac{1}{\sin^4(\theta/2)}

This relationship can be understood through the impact parameter: alpha particles passing closer to the nucleus experience stronger Coulomb repulsion and scatter through larger angles. The sin⁡4(θ/2)\sin^4(\theta/2) dependence emerges from the geometry of hyperbolic trajectories in an inverse-square force field.

The Variation with Scattering Angle

The plot of NN versus θ\theta shows a dramatic variation:

Scattering Angle θ\thetaRelative Number NNBehavior
Small (θ→0°\theta \to 0°)Very large (N→∞N \to \infty)Most particles undeflected
Moderate (θ≈30°−60°\theta \approx 30°-60°)ModerateNoticeable scattering
Large (θ≈90°−180°\theta \approx 90°-180°)Very smallRare backscattering events

The curve is steeply hyperbolic: at small angles, sin⁡(θ/2)≈θ/2\sin(\theta/2) \approx \theta/2 is small, so NN is enormous. As θ\theta increases toward 180° (backscattering), sin⁡(θ/2)→1\sin(\theta/2) \to 1, but the fourth power in the denominator means even at large angles the function drops precipitously.

A typical plot shows:

  • A near-vertical rise as θ→0°\theta \to 0°
  • Rapid decay for increasing θ\theta
  • A long tail extending to 180°, with non-zero (though tiny) counts even at backscattering angles
Tip

The experimental verification was quantitative: Geiger and Marsden measured NN at various angles and confirmed the sin⁡−4(θ/2)\sin^{-4}(\theta/2) dependence held over several orders of magnitude, validating Rutherford's nuclear model.

The Main Conclusion …

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