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Q.The figure shows a vm2v_m^2 versus 1λ\dfrac{1}{\lambda} graph for photoelectrons emitted from a surface, where vmv_m is the maximum speed of the electrons and λ\lambda is the wavelength of the incident radiation. Using this graph and Einstein's photoelectric equation, obtain the expressions for Planck's constant and the work function of the surface.

Figure — CBSE 2023 55/4/1 Q23
Figure
CBSECBSE Class XII Board 2023Subjective· 2mImportance★★★★★
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Einstein's photoelectric equation gives vm2=2hcm1λ−2ϕmv_m^2 = \frac{2hc}{m}\frac{1}{\lambda} - \frac{2\phi}{m}. The graph is a straight line; its slope gives Planck's constant h=mtan⁡θ2ch = \frac{m \tan\theta}{2c}, and its negative y-intercept gives the work function ϕ=m2∣intercept∣=hcλ0\phi = \frac{m}{2} |\text{intercept}| = \frac{hc}{\lambda_0}.

The photoelectric effect is one of those rare experiments where a single graph tells you two fundamental constants of nature. The key insight: Einstein said that light delivers energy in packets (hc/λhc/\lambda), and after paying the "exit fee" (the work function ϕ\phi), whatever energy remains shows up as the electron's kinetic energy. For the fastest electrons, that's 12mvm2\frac{1}{2} m v_m^2.

So the equation is:

12mvm2=hcλ−ϕ\frac{1}{2} m v_m^2 = \frac{hc}{\lambda} - \phi

Rearrange it to match the graph's axes (vm2v_m^2 vs 1/λ1/\lambda):

vm2=2hcm⋅1λ−2ϕmv_m^2 = \frac{2hc}{m} \cdot \frac{1}{\lambda} - \frac{2\phi}{m}

This is a straight line of the form y=(slope)x+cy = (\text{slope})x + c, where:

  • y=vm2y = v_m^2
  • x=1/λx = 1/\lambda
  • slope =2hcm= \frac{2hc}{m}
  • y-intercept =−2ϕm= -\frac{2\phi}{m}
Figure — CBSE 2023 55/4/1 Q23
Figure — CBSE 2023 55/4/1 Q23

Now read the graph.

  1. Slope from the graph. The line makes an angle θ\theta with the positive xx-axis, so its slope is tan⁡θ\tan\theta. Therefore:

tan⁡θ=2hcm\tan\theta = \frac{2hc}{m}

Solve for Planck's constant:

h=mtan⁡θ2ch = \frac{m \tan\theta}{2c}

  1. y-intercept from the graph. The dashed extension of the line hits the vm2v_m^2 axis at a negative value. Call the magnitude of this intercept II (so the intercept is −I-I). Then: −2ϕm=−I⇒ϕ=mI2-\frac{2\phi}{m} = -I \quad \Rightarrow \quad \phi = \frac{mI}{2} …

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