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Q.What are interstitial compounds? Give the classification of alloys with examples.

Maharashtra MsbshseMaharashtra HSC (MSBSHSE) Board 2023Subjective· 3mImportance★★★★★
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Interstitial compounds are metal lattices with small non-metal atoms trapped in the gaps; alloys are classified by how the second component is incorporated and by whether iron is present.

Interstitial compounds: compounds formed when small atoms such as hydrogen, carbon, nitrogen, or boron become trapped in the interstitial voids/spaces of a transition metal's crystal lattice, without disrupting the parent metallic structure. They typically retain metallic conductivity/lustre, are very hard, chemically inert, and have high melting points. Examples: TiCTiC, Fe3NFe_3N, Mn4NMn_4N, VH0.56VH_{0.56}, TiH1.7TiH_{1.7} (used in steel-making and as hard, refractory materials).

Classification of alloys:

  1. Homogeneous alloys (solid solutions):
    • Substitutional alloys — atoms of similar size replace host metal atoms in the lattice, e.g. brass (Cu–Zn), bronze (Cu–Sn).
    • Interstitial alloys — small atoms occupy the interstitial voids of the host metal lattice, e.g. steel (Fe with interstitial C). …

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