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Question 97 of 106

Q.Write the preparation of potassium dichromate from chromite ore.

Maharashtra MsbshseMaharashtra HSC (MSBSHSE) Board 2024Subjective· 3mImportance★★★★★
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Chromite →\rightarrow (fuse w/ Na2_2CO3_3/air) Na2_2CrO4_4 →\rightarrow (acidify) Na2_2Cr2_2O7_7 →\rightarrow (+KCl) K2_2Cr2_2O7_7.

Preparation of potassium dichromate from chromite ore (FeCr2O4FeCr_2O_4):

Step 1 — Fusion (roasting) with sodium carbonate in air: converts chromite to soluble sodium chromate.

4FeCr2O4+8Na2CO3+7O2→Δ8Na2CrO4+2Fe2O3+8CO24FeCr_2O_4 + 8Na_2CO_3 + 7O_2 \xrightarrow{\Delta} 8Na_2CrO_4 + 2Fe_2O_3 + 8CO_2

Step 2 — Acidification: the aqueous extract of sodium chromate is acidified with sulfuric acid, converting yellow chromate to orange dichromate.

2Na2CrO4+H2SO4⟶Na2Cr2O7+Na2SO4+H2O2Na_2CrO_4 + H_2SO_4 \longrightarrow Na_2Cr_2O_7 + Na_2SO_4 + H_2O

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